1.1. Product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier providing the safety data sheet
Address: 119, Boulevard Felix Faure. 93300 AUBERVILLIERS CEDEX FRANCE
Telephone: 33.1.48.11.70.00. Fax: 33.1.48.33.28.79. Telex:.
1.4. Emergency telephone number: +44 (0) 1235 239 670.
Company / Company: ORFILA.
2.1. Classification of the substance or mixture
Meets Regulation (EC) No 1272/2008 and its adaptations.
Skin irritation category 2 (Skin Irritation 2, H315).
Eye irritation, Category 2 (Eye Irritation 2, H319).
This mixture carries no physical risk. See recommendations for other local products.
This mixture does not pose an environmental risk. Under normal conditions of use, no environmentally harmful effect is known or
predictable.
2.2. Label elements
Meets Regulation (EC) No 1272/2008 and its adaptations.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of the reach of children.
P264 Wash hands thoroughly after use.
P280 Wear protective gloves / protective clothing / eye protection / face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Perhaps
Remove contact lenses, if possible. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice / attention.
P337 + P313 If eye irritation persists: Get medical advice / attention.
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2.3. Other dangers
The mixture does not contain any "very serious substances" (SVHC)> = 0,1% published by the European Chemical Agency (ECHA)
The mixture does not comply with the criteria applied to the PBT and vPvB blends, in accordance with Annex XIII of the
REACH Directive (EC) No. 1907/2006.
3.2. mixtures
Acute Tox. 4, H302
2-BUTOXYETHANOL Acute Tox. 4, H312
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Acute Tox. 4, H332
[1] Substance for which there are exposure limits in the workplace.
In case of doubt or if symptoms persist consult a doctor.
Never give anything by mouth to an unconscious person.
4.1. Description of first aid measures
Thoroughly rinse with soft, clean water for at least 15 minutes with the eyelid open.
For complaints, redness or visual impairment consult an ophthalmologist.
Remove contaminated clothing and skin thoroughly with soap and water or a suitable detergent
Wash.
Look for product residue between skin and clothing, watch, shoes, etc.
In the event of extensive contamination and / or skin injury, a doctor must be consulted or the affected person must be hospitalized
be transferred.
Nothing to take over the mouth.
When taking small amounts (not more than one sip) rinse mouth with water and consult a doctor.
Call a doctor immediately and show him the label.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
No information available.
Not flammable.
5.1. extinguishing Media
5.2. Special hazards arising from the substance or mixture
Fire often produces dense, black smoke. Exposure to decomposition products can be detrimental to health.
In case of fire can form:
Carbon monoxide (CO)
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- carbon dioxide (CO2)
5.3. Advice for firefighters
No information available.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Follow protective measures in sections 7 and 8.
For non-rescue personnel
Avoid contact with skin and eyes.
For rescue personnel
The operator must be equipped with appropriate personal protective equipment (see section 8).
6.2. Environmental precautions
Stop and trap leaks or spills with liquid-binding, non-combustible material, eg: sand, earth,
Universal binder, diatomaceous earth in drums for disposal of waste.
Prevent entry into sewers or waters.
6.3. Methods and material for containment and cleaning
In the event of soil contamination and after collecting the product by soaking in a neutral, non-combustible binder, soiled surface
wash with plenty of water.
Preferably clean with a detergent, do not use organic solvents.
6.4. Reference to other sections
No information available.
SECTION 7: HANDLING AND STORAGE
For the premises where the mixture is used, the provisions for deposits apply.
7.1. Precautions for safe handling
Wash hands after each use.
Remove contaminated clothing before reuse and wash.
Information about fire and explosion protection :
Prevent access for unauthorized persons.
Advice for safe handling :
For personal protection, see section 8.
Observe the information of the label and regulations of occupational safety.
Do not bring mixture into contact with skin and eyes.
Inadmissible equipment and method of operation:
Smoking, eating and drinking are prohibited in the premises where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
No information available.
storage
Keep out of reach of children.
packaging
Always keep the product in a packaging that matches the original packaging.
7.3. Specific end uses
No information available.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Parameters to be monitored
Occupational exposure limits:
- European Union (2017/164 / UE, 2009/161 / UE, 2006/15 / CE, 2000/39 / CE, 98/24 / CE)
CAS VME mg / m3: VME ppm: VLE mg / m3: VLE ppm: Notes:
111-76-2 98 20 246 50 Peau
- ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010):
CAS TWA: STEL: upper limit: definition: criteria:
111-76-2 20 ppm A3; WHEN
- Germany - AGW (BAuA - TRGS 900, 21/06/2010):
CAS - short-term limit Upper limit: exceeded
value: factor:
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111-76-2 10 ppm 4 (II)
49 mg / m3
- France (INRS - ED984: 2012):
CAS VME ppm: VME mg / m3: VLE ppm: VLE mg / m3: Notes: TMP N °:
111-76-2 10 49 50 246 * 84
8.2. Limitation and monitoring of exposure
Personal protective measures such as personal protective equipment
Pictogram (s) for compulsory personal protective equipment (PPE):
Use clean and properly maintained personal protective equipment.
Keep personal protective equipment in a clean place, away from the work area.
Do not eat, drink or smoke while using. Remove contaminated clothing before reuse and wash. For
ensure adequate ventilation, especially in confined spaces.
- Protection for eyes / face
Avoid contact with eyes.
Use eye protection against liquid splashes.
Each use must be carried out in accordance with standard EN 166 safety goggles with side protection.
In case of increased risk, use a face shield to protect the face.
Wearing a prescription glasses is no protection.
Contact lens wearers are recommended to use corrective lenses during work that may produce irritating vapors.
Eye shower systems in the premises in which the product is used, provide.
- Hand protection
For long-term or repeated skin contact wear suitable protective gloves.
Use suitable chemical resistant gloves according to standard EN 374.
Gloves should be selected according to use and duration of use at the workplace.
Protective gloves must be selected according to the workplace: other chemicals could be changed, required
physical protective measures (cutting, stinging, thermal protection), required dexterity.
Recommended properties:
- Impermeable gloves according to standard EN 374
- Body protection
Avoid skin contact.
Wear suitable protective clothing.
Type of suitable protective clothing:
With strong syringe
Type of suitable protective clothing:
In case of heavy spraying wear liquid-tight chemical protective clothing (type 3) according to EN 14605 to avoid any skin contact.
In case of danger of splashing wear chemical protective clothing (type 6) according to EN 13034 to avoid any skin contact.
The staff has to wear regularly washed work clothes.
After contact with the product, all soiled parts of the body must be washed.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on the basic physical and chemical properties
General Information :
Form: low-viscosity liquid
Color: colorless
Important information on health, environmental protection and safety:
pH: not relevant.
Flash point: 94.00 ° C.
Vapor pressure (50 ° C): below 110 kPa (1.10 bar)
Density: = 1
Water solubility: Partially soluble.
Viscosity: v <7 mm2 / s (40 ° C)
9.2. Other Information
No information available.
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
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No information available.
10.2. Chemical stability
This mixture is stable if it adheres to the recommended handling and storage instructions in section 7.
10.3. Possibility of dangerous reactions
No information available.
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
The thermal decomposition can release / form:
Carbon monoxide (CO)
- carbon dioxide (CO2)
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
May cause reversible skin damage, such as dermatitis or redness and scabbing or onset
edema as a result of exposure for up to 4 hours.
May cause reversible effects on the eye, such as eye irritation, which will be complete within a 21-day observation period
regresses.
11.1.1. matter
Acute toxic effect:
2-BUTOXYETHANOL (CAS: 111-76-2)
Oral: LD50 = 470 mg / kg
Type: rat
Dermal: LD50 = 1100 mg / kg
Inhalation (vapors): LC50 = 11 mg / l
11.1.2. mixture
There is no toxicological information available for the mixture.
SECTION 12: ECOLOGICAL INFORMATION
12.1. toxicity
12.1.1. substances
2-BUTOXYETHANOL (CAS: 111-76-2)
Toxicity to fish: LC50 = 1490 mg / l
Species: Lepomis macrochirus
Exposure duration: 96 h
12.1.2. mixtures
There is no information on aquatic toxicity for the mixture.
12.2. Persistence and degradability
12.2.1. matter
2-BUTOXYETHANOL (CAS: 111-76-2)
Biodegradation: Fast biodegradable.
12.3. Bioaccumulative
12.3.1. matter
2-BUTOXYETHANOL (CAS: 111-76-2)
Octanol / water partition coefficient: log Koe = 0.81
12.4. Mobility in the ground
No information available.
12.5. Results of PBT and vPvB assessment
No information available.
12.6. Other adverse effects
No information available.
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No information available.
10.2. Chemical stability
This mixture is stable if it adheres to the recommended handling and storage instructions in section 7.
10.3. Possibility of dangerous reactions
No information available.
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
The thermal decomposition can release / form:
Carbon monoxide (CO)
- carbon dioxide (CO2)
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
May cause reversible skin damage, such as dermatitis or redness and scabbing or onset
edema as a result of exposure for up to 4 hours.
May cause reversible effects on the eye, such as eye irritation, which will be completed within a 21-day observation period
recourse.
11.1.1. matt
Acute toxic effect:
2-BUTOXYETHANOL (CAS: 111-76-2)
Oral: LD50 = 470 mg / kg
Type: rat
Dermal: LD50 = 1100 mg / kg
Inhalation (vapors): LC50 = 11 mg / l
11.1.2. mixture
There is no toxicological information available for the mixture.
SECTION 12: ECOLOGICAL INFORMATION
12.1. toxicity
12.1.1. substances
2-BUTOXYETHANOL (CAS: 111-76-2)
Toxicity to fish: LC50 = 1490 mg / l
Species: Lepomis macrochirus
Exposure duration: 96 h
12.1.2. Mixtures
There is no information on aquatic toxicity for the mixture.
12.2. Persistence and degradability
12.2.1. matt
2-BUTOXYETHANOL (CAS: 111-76-2)
Biodegradation: Fast biodegradable.
12.3. bioaccumulative
12.3.1. matt
2-BUTOXYETHANOL (CAS: 111-76-2)
Octanol / water partition coefficient: log Koe = 0.81
12.4. Mobility in the ground
No information available.
12.5. Results of PBT and vPvB assessment
No information available.
12.6. Other adverse effects
No information available.
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No information available.
10.2. Chemical stability
This mixture is stable if it adheres to the recommended handling and storage instructions in section 7.
10.3. Possibility of dangerous reactions
No information available.
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
The thermal decomposition can release / form:
Carbon monoxide (CO)
- carbon dioxide (CO2)
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
May cause reversible skin damage, such as dermatitis or redness and scabbing or onset
edema as a result of exposure for up to 4 hours.
May cause reversible effects on the eye, such as eye irritation, which will be completed within a 21-day observation period
recourse.
11.1.1. matt
Acute toxic effect:
2-BUTOXYETHANOL (CAS: 111-76-2)
Oral: LD50 = 470 mg / kg
Type: rat
Dermal: LD50 = 1100 mg / kg
Inhalation (vapors): LC50 = 11 mg / l
11.1.2. mixture
There is no toxicological information available for the mixture.
SECTION 12: ECOLOGICAL INFORMATION
12.1. toxicity
12.1.1. substances
2-BUTOXYETHANOL (CAS: 111-76-2)
Toxicity to fish: LC50 = 1490 mg / l
Species: Lepomis macrochirus
Exposure duration: 96 h
12.1.2. Mixtures
There is no information on aquatic toxicity for the mixture.
12.2. Persistence and degradability
12.2.1. matt
2-BUTOXYETHANOL (CAS: 111-76-2)
Biodegradation: Fast biodegradable.
12.3. bioaccumulative
12.3.1. matt
2-BUTOXYETHANOL (CAS: 111-76-2)
Octanol / water partition coefficient: log Koe = 0.81
12.4. Mobility in the ground
No information available.
12.5. Results of PBT and vPvB assessment
No information available.
12.6. Other adverse effects
No information available.
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No information available.
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German Ordinance on the Classification of Water Hazard (WGK):
WGK 1 (VwVwS of 27/07/2005, KBws): Slightly hazardous to water.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste from the mixture and / or its container (s) must be disposed of in accordance with the provisions of Directive 2008/98 / EC.
13.1. Waste treatment method
Do not discharge into drains or waters.
Waste:
Waste disposal must be carried out without risks to humans and the environment, in particular to water, air, soil, fauna and flora.
Disposal or recovery in accordance with valid legislation preferably by an authorized waste collector or a
Waste management company.
Do not contaminate soil or groundwater, do not dispose of waste in the environment.
Dirty packaging:
Dispose of containers only when empty. Do not remove the label (s) on the container.
Return to an authorized disposal company.
SECTION 14: TRANSPORT INFORMATION
Not dangerous goods in terms of transport regulations.
14.1. UN number
-
14.2. UN proper shipping name
-
14.3. Transport hazard class
-
14.4. packaging group
-
14.5. environmental hazards
-
14.6. Special precautions for the user
-
SECTION 15: LEGISLATION
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
Information regarding classification and labeling can be found in Section 2 A19:
The following guidelines have been considered:
- Regulation (EC) No 1272/2008, as amended, as Regulation (EU) No 2016/1179. (ATP 9)
Information regarding the packaging:
No information available.
- Special provisions:
No information available.
German Ordinance on the Classification of Water Hazard (WGK):
Water hazard class: slightly hazardous to waters WGK 1 (VwVwS vom 27/07/2005, KBws)
15.2. Chemical Safety Assessment
No information available.
SECTION 16: OTHER INFORMATION
Since we have no information about the working conditions of the user, the information is based on this
Safety data sheet on the state of our knowledge and the national and EC regulations.
Without written instructions on handling in advance, the mixture may only be used for the uses referred to in heading 1
become.
The user is responsible for taking all necessary measures to comply with legal requirements and local
Regulations.
The information in this safety data sheet is intended as a description of the safety requirements for this mixture
and not as a guarantee of its properties.
Wording of the sentences in Section 3:
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H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful by inhalation.
Abbreviations:
ADR: European Convention on the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Dangerous Goods.
IATA: International Air Transport Association.
OACI: International Civil Aviation Organization.
RID: Regulations concerning the International carriage of dangerous goods by rail.
WGK: Water hazard class.
GHS07: Exclamation mark
PBT: Persistent, bioaccumulating and toxic.
vPvB: Very persistent and very bioaccumulative.
SVHC: Very worrying substance.
