I've listed the process in some detail in the hope that some bright spark can tell me where I went wrong.
Took a year to fix the body shell and I used Halfords spray paints (etch, primer and gloss) to seal the panels while the repairs were finished.
2k high build primer applied once the repairs were finished and it immediately reacted with one of the many gloss cans I'd used, not a crinkle reaction but it pulled back in a crinkle pattern.
Sanded down the high build and applied a thin coat of Barcoat paint.
2k high build over the top of this. No reaction, sanded with 400 grade.
Several thin coats of 2k over the top and all looked well.
All paint applied in warm dry conditions with each application of primer on a separate day. The last application of primer had a week to dry before the top coat was applied. 5-6 thin colour coats all applied on the same day.
Six weeks after polishing I've had three different reactions starting to become apparent.
Very small pin holes started to appear on the front wings and rear panel. They look like miniature meteorite craters.
[attachment=87834:P1070758_b.JPG]
Pot marks on both A panels (rear edge of both). Flat bottomed.
[attachment=87835:P1070774_b.JPG]
Ripples appearing (very difficult to photograph). Looks like ripples left in the shallows on a sandy beach but on a very very small scale. At the moment these ripples are still developing and spreading after spraying in the last week of April.
Now the paint was near as damn it perfect when I'd finished the cutting and polishing and the imperfections were not there. The puzzling thing is the length of time they took to appear. Had they shown on the day of spraying or the following day I could understand the problem but a month and a half? To make it more interesting none of these problems have appeared where I had the first reactions with the Halfords paint.
I'm resigned to sanding the car back to metal and starting again but I'd like to know what went wrong. The atmosphere was dry, the air supply filtered and had a water trap. There were no silicones or other contaminates in the garage or on the car. The paint, activators, thinners and all additional materials came from a reputable supplier. The paint is fine on the doors, boot lid and bonnet but these were all treated in the same way, there is no difference in materials or the process.
Does anybody have an idea of what I did wrong?
And it was all beginning to look rather good.....

[attachment=87843:P1070776_c.JPG]