when looking at the power rating (watts) RMS is the figure you want to use. Peak or PMPO is just a ******* value made to make look cheap speakers and amps look good.
For the focals which are 40wrms you need an amp capable of providing that amount on each channel.
For the subs which are 120wrms you need an amp capable of providing that to two channels.
You can however run them in parallel at two ohms which would be around 250wrms each. So you'd need amp capable of providing 500wrms @2ohm. This could be a two channel amp bridging the outputs, or a monoblock amp (single channel)
Regarding head unit, stay away from sony. I would suggest Pioneer.
You may be lacking some midbass up front with only 4" drivers, if you could fit some 6" woofers up there it would sound much nicer. The 8's will provide some mid and not much sub bass as they only go down to 30Hz so might sound OK. I would honestly return the 4" focals for some 6" splits you will get a much nicer sounding system.
For amps you may be able to find a budget solution - in Australia we have a shop called Jaycar selling Response Amps, which are good bang for buck amps which have won awards in several ICE/CA mags. Not sure if that equipment is available in the UK but there may be some kind of an alternative.
Jaycar in Aus do have a UK page set up with UK prices and seem to ship to UK.
http://jaycar.co.uk/...&keyform=CAT2#4