I can't see from the picture exactly what you have done, and am assuming that it is plumbed the only way that can possibly work, with the feed from the PRV going in where the reservoir would be, and the output to the rear brakes from the normal outlet on the new master cylinder. If that is so, and it will not bleed, it is possibly due to the pipe layout, as if there is a high point in which air can become trapped, it will take a very large amount of fluid displacement and a high flow rate to shift it. By using a master cylinder that way, you have only a very limited flow rate and displacement. Even using a pressure bleeder, you will not get a good flow rate, due to the restriction imposed by the small bore of the reservoir port drilling in the master cylinder.
There are also serious problems with that installation, and your car in general. Does your insurance company know about what is very clearly a bodge in the brake system? And are you using COPPER pipe, itself unsatisfactory, without adequate support?
I could tell you exactly what to do to make it bleedable, but I am not going to do so, and instead suggest that as you clearly do not understand the implications of what you are doing, you return the car to standard specification forthwith, and make the roads safer for us all.