I would tend to say neither - blue is what you want! You basically want good old ethylene glycol based anti-freeze for an old car like a mini, which in my experience is always a blue colour. As far as I can tell from a bit of googling though, green is the new blue and should be ethylene glycol. Stay away from the orange, which is OAT - Organic Acid Technology - that isn't really mini friendly. Might not cause an issue with the engine or head, but not so good for Radiators or heater matrix, it is not compatible with old style radiators.
What is in there just now? in any case I would give it all a good flushing through and use Blue (or green if you can establish it is ethylene glycol) coolant, either pre-mixed or a 50/50 mix with water.