Yes, the MOT history is really helpful. If there was serious rust noted in, say, 2012 but not 2013, was it properly repaired with panels cut out and new metal welded in? Or was it just covered in underseal or patched over? You can go to look at a car forewarned for close investigation.
Minis rust from the inside out, so any rust in the seams below the headlights, on the A panels, etc, has probably started from inside. It's not simply 'surface rust'. Bear in mind however that new panels are cheap - the cost is in getting them welded on and painted if you're not going to do that yourself.
Check the sills to make sure that the correct type is fitted. As built (except for 1959 cars!!) they have open flutes / 'vents' under the car which allow water and condensation to drain out. Often these sills have been replaced with 'wide' oversills that have raised squares but no vents. These don't allow the water out with the risk that the floor starts to rot. They also change the structural box section. Sometimes they have been welded straight over the old rusty sill to pass an MOT (hence the name oversill). Watch out for these sills. (see http://www.theminifo...-to-avoid-them/)
There are some photos at http://www.itsamini.co.uk/check.htm
As above, a good inspection of the underside once a year plus inject wax into all the cavities (there are lists on here) will do a lot to help.
The most important thing is not to rush and buy the first car you see if you have any doubts!