I am all for upskilling and the ability to weld is a good tool to have in the box, but like most skills it takes some time to master. An experienced hand may make it look easy but to make a success of things takes many hours of practice.
Remember it is not just a welder you need, PPE, a variety of cutting tools, grinding tools clamps and clips etc are also needed.
Practicing on good clean steel on the bench is just a start but it is a far cry from actually welding a rusty vehicle. Everyone has to start somewhere so if you feel confident that you can master the skills needed then go for it.
There will be every chance that once you cut off the sills, with whatever equipment you have purchased, that underneath there will be more rust that will need addressed before the new outer sills are fitted, thus leading to more metalwork skills needed.
If it is only the sills you want to replace then it may be worth just getting a reputable workshop to carry out the work, but remember to get a good job you cannot expect this work to be cheap, cutting off the sills can be like opening a can of worms. If you fear the workshop is going to rip you off then do not employ them, use someone else, or ask to see things once the sills are removed and reassess the job.
The choice is yours but if you foresee the need for this kind of work in the future them invest in the equipment and time, the rewards of seeing a nicely repaired panel are worth it, but there is nothing worse than looking at "old indians", "apatchy" as we say in the trade.