As the system is essentially closed, it needs air to be let in to let it leak or some pressure in the system.
Pressurise the system and have a look to see if you can identify where it's leaking from. There are commercial tools for this, but if you have a hand or foot tyre pump these often have a chuck on them that has a rubber in them and a lever to lock them on the tyre valve. These will also fit on to the overflow on the Radiator, you may need a different Radiator Cap to get a seal where you need it, but you can use this arrangement to pressurise the system. Ideally use a pump that has a gauge, take it up to 15 PSI.
Did not think of the footpump method. I ended up running the car to build up pressure. Car ran for 15mins but no leak.
Question, other than the overflow tank, are there other outlets for excess coolant to be dissipated?