The best thing for bleed nipples I think (and also the brake adjusters, for which I did once have a special square spanner but which I can't seem to find) is the small Knippex wrench pliers. They're actually gripping the thing with positive force and not relying on just being the right size so you get a much better purchase and no risk of rounding.
My socket set dates from the 90s and has a full set of metric and imperial everything, and before getting my Mini sorted a few years ago, I got some imperial ratchet spanners (very useful for the hard-to-reach things like the fuel pump and exhaust clamp) and some imperial open/ring spanners, although I had a few from back in the day. They're perfectly easy to get hold of in UK.
Here is a conversion table. A 19 is actually within the lower tolerance for a 3/4 (the lower tolerance is usually about 0.05mm), so they are really interchangeable, but at the upper end, according to ISO, spanners are allowed to be about 0.2mm too big (the exact amount varies according to the size). That means a 5 on a 3/16 is just about OK, an 8 on a 5/16 is fine, as is a 16 on a 5/8-- if you have a 16, 17 is a much more common size. You might get away with a 13 on a 1/2, but I don't like it. YMMV.
inches mm rounded-up too big by (in mm)
3/16 4.762 5 0.238
1/4 6.350 7 0.650
5/16 7.938 8 0.062
3/8 9.525 10 0.475
7/16 11.112 12 0.888
1/2 12.700 13 0.300
9/16 14.287 15 0.713
5/8 15.875 16 0.12511/16 17.462 18 0.538
3/4 19.050 20 0.950
That's a great little chart, thanks for posting it here.
What also needs to be kept in mind is that spanners aren't vernier accurate either, they are purposely made a wee bit over size to allow for some light corrosion, gunk, small burrs and an easy fit, ie, if you tied to fit say a 1/2" spanner to a 1/2" Hex and these were exact sizes or even if they had 2 thou clearance, you'd curse the spanner every time you picked it up. I've not looked in to it too closely to see what the rule of thumb for these clearances are, but it's there and on a sliding scale depending on the sizes.