Sorry Minilee94. Quick check with a straight edge, long metal rule but be sure to do it across the diagonals as well as straight across long ways and then at intervals across the face. Get your eyes down and look for gaps where the edge of the rule sits on the face. More involved check for flatness would be on a surface table with engineer's blue but thats not practical. Basically you are trying to ensure its as flat as possible.
Ideally remove the valves and look into the ports, around the valve seats for cracking. Look up ports again for signs of cracking.
As for over skimming, visually are he combustion chambers reasonably deep. If they look very shallow then it may be too hard to achieve a low enough CR for proper running on normal fuel. Also look at thickness of head through the water passages.
Get your engine tuner / head man to check it and see if the seller would take it back if it is not good when checked.
Others on here may offer you some more advice. Hope it's a good one.
A steel rule will tell you nothing, as they can be more bent than the head, I have been given loads of heads to skim only to find out that they are not warped, bowed or twisted in any way, and yes I do advise the customer......
The head thickness is 2.75"