You should never use those, and they should not be sold. The spacer should only be supplied with the pair of bearings it was supplied with as a matched set, as it is used to take up manufacturing tolerances in individual bearings. If you fit a standard spacer, the running clearances will almost always be too tight or too loose, both of which will result in a short bearing life. Too tight, in particular, is likely to lead to a serious accident when the bearing overheats badly and the stub axle collapses.
A large proportion of the bearing problems reported here are probably due to one size of spacer being supplied with arbitrarily paired bearings.