So, a little update.. today I fitted a new 11 blade fan, 82 degree stat, flushed the system and radiator again, then re-filled with fresh coolant (approx. 75/25 - water/coolant respectively)
I left the car to idle, it came up to temp and held just above N, went to take it for a drive and the same thing happened again - before I got to the end of my road (approx. 300 yards) the temp gauge had shot up over H. I turned around and rolled back outside the house, temp immediately started to drop and went back down to just over N.
I have an aux fan coming, hopefully will arrive tomorrow and I'll fit that, but clearly there is another issue here as the engine shouldn't be heating up (or cooling down?) that quickly. I'm minded to think Cooperman was right regarding the gauge reading incorrectly so I'll also get a capillary gauge ordered, though I do think it's also getting hot, even if the gauge is exaggerating that somewhat.